Application of 172222-30-9, An article , which mentions 172222-30-9, molecular formula is C43H72Cl2P2Ru. The compound – Benzylidenebis(tricyclohexylphosphine)dichlororuthenium played an important role in people’s production and life.
Ruthenium carbene complexes featuring the bulky tridentate N,N?-bis(2,6-diisopropylphenyl)-2,6-pyridinedicarboxamido pincer-type ligand and different stabilizing phosphine ligands were synthesized and characterized. Preliminary results for the application to ring-closing metathesis show low activity for the cyclization of 1,7-octadiene with benzylidene(triphenylphosphine)[N,N?-bis(2,6-diisopropylphenyl)-2, 6-pyridinedicarboxamido-kappa3O,N,O/O,N,N]ruthenium(II) (4a,b). Benzylidene(tricyclohexylphosphine)[N,N?-bis(2,6-diisopropylphenyl) -2,6-pyridinedicarboxamido-kappa33O,N,O]ruthenmm(II) (5) successfully transformed 1,7-octadiene to cyclohexene and ethylene in good yields at room temperature or 80C.
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Reference：
Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI