In an article, published in an article, once mentioned the application of 32993-05-8, Name is Chlorocyclopentadienylbis(triphenylphosphine)ruthenium(II),molecular formula is C41H35ClP2Ru, is a conventional compound. this article was the specific content is as follows.Recommanded Product: Chlorocyclopentadienylbis(triphenylphosphine)ruthenium(II)
The heterobimetallic Ru/Pd, Ru/Pt, Ru/Au and Ru/Cu complexes Cp(PPh3)Ru(mu-I)(mu-dppm)PdCl2 (4), Cp(PPh3)Ru(mu-Cl)(mu-dppm)Pd(CH3)Cl (5), Cp(PPh3)Ru(mu-I)(mu-dppm)PtCl2 (6), Cp(PPh3)Ru(mu-I)(mu-dppm)PtI2 (7), Cp(PPh3)RuI(mu-dppm)AuI (8), Cp(PPh3)RuBr(mu-dppm)AuCl (9), Cp(PPh3)RuCl[mu-PPh2(CH2)4 PPh2]AuCl (10), Cp(PPh3)RuCl(mu-Ph2 PNHPPh2)AuCl (11) and Cp(PPh3)Ru(mu-I)(mu-dppm)CuI (12) were prepared by the reactions of CpRu(PPh3)(eta1-Ph2PQPPh2)X [Q = (CH2)n (n = 1, 4), NH; X = Cl, Br, I, Me] with Pd(COD)Cl2, Pt(COD)Cl2, Pt(COD)I2, Au(PPh3)Cl, AuI, AuCl and CuI, respectively. The structures of compounds 4, 5, 10 and 12 were determined by X-ray crystallography. Cyclic voltammetry of the halide-bridged complexes revealed shifts in the redox potentials of the metals, as compared to mononuclear model compounds. The shifts are consistent with electron donation between the metals through the halide bridge. Ru/Au complexes 8-11, which are bridged only by the bidentate phosphine, exhibited minimal electronic effects between the metal centers. This limited interaction between the metal centers in 8-11 is corroborated by UV/vis spectroscopy.
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Reference：
Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI