Month: May 2021

Reference of 37366-09-9, Chemistry can be defined as the study of matter and the changes it undergoes. You’ll sometimes hear it called the central science because it is the connection between physics and all the other sciences, starting with biology.37366-09-9, Name is Dichloro(benzene)ruthenium(II) dimer, molecular formula is C12H12Cl4Ru2. In a patent, introducing its new discovery.

Three series of heterodinuclear ruthenium-iron complexes have been synthesized from (eta6-arene)ruthenium dichloride dimers and phosphinoferrocene ligands containing glycine-based carboxamido substituents. The neutral complexes [(eta6-arene)RuCl2(Ph 2PfcCONHCH2CO2Me-kappaP)] (4, arene = benzene (a), p-cymene (b), hexamethylbenzene (c); fc = ferrocene-1,1?-diyl) were obtained by the bridge cleavage reaction of [(eta6-arene)RuCl 2]2 with Ph2PfcCONHCH2CO 2Me (1) in chloroform solution. The complex [(eta6-p- cymene)RuCl2(Ph2PfcCONHCH2CONH 2-kappaP)] (6b) was synthesized in the same way from Ph 2PfcCONHCH2CONH2 (3); the preparation of [(eta6-p-cymene)RuCl2(Ph2PfcCONHCH 2CO2H-kappaP)] (5b), featuring the ferrocene ligand in the free acid form (2), failed due to side reactions and isolation problems. The salts [(eta6-arene)RuCl(MeCN)(1-kappaP)][PF6] (7a-c) and [(eta6-arene)Ru(MeCN)2(1-kappaP)][PF 6]2 (8a-c) were prepared from 1 and the acetonitrile precursors [(eta6-arene)RuCl(MeCN)2][PF6] and from 4a-c via halide removal with Ag[PF6] in acetonitrile solution, respectively. Alternative synthetic routes to 7b and 8b were also studied. The compounds were fully characterized by elemental analysis, multinuclear NMR, IR, and electrospray ionization mass spectra, and their electrochemical properties were studied by cyclic voltammetry at a Pt-disk electrode. The single-crystal X-ray analyses of two representatives (4b and 8b) revealed a pseudotetrahedral coordination geometry at the ruthenium centers and eclipsed conformations of the ferrocene moieties, with the substituents at the two cyclopentadienyl rings being anti with respect to each other. All complexes showed high activity for the catalytic oxidation of secondary alcohols with tert-butyl hydroperoxide to give ketones in aqueous media. The most active catalyst was obtained from the neutral p-cymene complex 4b, showing a catalytic turnover frequency of 13 200 h-1 at room temperature for the oxidation of 1-phenylethanol at a substrate/catalyst ratio of 100 000.

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Reference：
Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI

Children learn through play, and they learn more than adults might expect. Science experiments are a great way to spark their curiosity, get their minds active, and encourage them to do something that doesn’t involve a screen. 32993-05-8, C41H35ClP2Ru. A document type is Article, introducing its new discovery., COA of Formula: C41H35ClP2Ru

Ruthenium complexes [(eta5-C5H5)Ru(kappa1-P-PPh2Py)(PPh3)Cl] (1) and [(eta5-C5H5)Ru(kappa2-P-N-PPh2Py)(PPh3)]+ (1a) containing diphenyl-2-pyridylphosphine (PPh2Py) are reported. Coordinated PPh2Py in the complex [(eta5-C5H5)Ru(kappa1-P-PPh2Py)(PPh3)Cl] (1) exhibits monodentate behavior. In presence of NH4PF6 in methanol at room temperature it afforded chelated complex [(eta5-C5H5)Ru(kappa2-P,N-PPh2Py)(PPh3)]+ (1a). Further, 1 reacted with various species viz., CH3CN, NaCN, NH4SCN and NaN3 to afford cationic and neutral complexes [(eta5-C5H5)Ru(kappa1-P-PPh2Py)(PPh3)L]+ and [(eta5-C5H5)Ru(kappa1-P-PPh2Py)(PPh3)L] [L = CH3CN (1b); CN- (1c); N3- (1d) and SCN- (1e)] and it’s reaction with N,N-donor chelating ligands dimethylglyoxime (H2dmg) and 1,2-phenylenediamine (pda) gave cationic complexes [(eta5-C5H5)Ru(kappa1-P-PPh2Py)(kappa2-N-N)]PF6 [kappa2-N-N = dmg (1f) and pda (1g)]. The complexes 1-1g have been characterized by physicochemical techniques and crystal structures of 1, 1a, 1c, 1e and 1f have been determined by single crystal X-ray analyses. Catalytic potential of the complex 1 has been evaluated in water under aerobic conditions. It was observed that the complex 1 selectively catalyzes reduction of aldehyde into alcohol.

Interested yet? Keep reading other articles of 32993-05-8!, COA of Formula: C41H35ClP2Ru

Reference：
Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI

Synthetic Route of 246047-72-3. Chemistry is an experimental science, and the best way to enjoy it and learn about it is performing experiments.Introducing a new discovery about 246047-72-3, Name is (1,3-Bis(2,4,6-trimethylphenyl)-2-imidazolidinylidene)dichloro(phenylmethylene)(tricyclohexylphosphine)ruthenium

This paper reports the synthesis and characterization of a variety of ruthenium complexes coordinated with phosphine and N-heterocyclic carbene (NHC) ligands. These complexes include several alkylidene derivatives of the general formula (NHC)(PR3)(Cl)2Ru=CHR?, which are highly active olefin metathesis catalysts. Although these catalysts can be prepared adequately by the reaction of bis(phosphine) ruthenium alkylidene precursors with free NHCs, we have developed an alternative route that employs NHC-alcohol or -chloroform adducts as “protected” forms of the NHC ligands. This route is advantageous because NHC adducts are easier to handle than their free carbene counterparts. We also demonstrate that sterically bulky bis(NHC) complexes can be made by reaction of the pyridine-coordinated precursor (NHC)(py)2(Cl)2Ru=CHPh with free NHCs or NHC adducts. Two crystal structures are presented, one of the mixed bis(NHC) derivative (H2IMes)(IMes)(Cl)2Ru=CHPh, and the other of (PCy3)(Cl)(CO)Ru[eta2-(CH2- C6H2Me2)(N2 C3H4)(C6H2Me3)], the product of ortho methyl C-H bond activation. Other side reactions encountered during the synthesis of new ruthenium alkylidene complexes include the formation of hydridocarbonyl-chloride derivatives in the presence of primary alcohols and the deprotonation of ruthenium vinylcarbene ligands by KOBut. We also evaluate the olefin metathesis activity of NHC-coordinated complexes in representative RCM and ROMP reactions.

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Reference：
Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI

Related Products of 14564-35-3. Let’s face it, organic chemistry can seem difficult to learn. Especially from a beginner’s point of view. Like 14564-35-3, Name is Dichlorodicarbonylbis(triphenylphosphine)ruthenium(II). In a document type is Article, introducing its new discovery.

The tridentate ligand 2,6-diallylpyridine (DAP) has been used to synthesize novel complexes of iridium(I), ruthenium(II), palladium(II) and platinum(II) of formulae , , ClO4, , PdCl2(DAP)2>, .All the complexes have been characterized by elemental analysis.IR, and 1H NMR spectroscopy.The molecular structures of and have been determined by single-crystal X-ray diffraction studies.Crystals of the ruthenium complex are orthorhombic, space group Pbca, with Z=8 in a unit cell of dimensions a 11.492(5), b 18.942(3), c 23.083(9) Angstroem.Crystals of the palladium complex are triclinic, space group <*> with Z=1 in a unit cell of dimensions a 7.950(4), b 8.745(4), c 9.578(4) Angstroem, alpha 113.02(3), beta 90.75(3), gamma 116.65(3)o.Both structures were solved by Patterson and Fourier methods and refined by blocked full-matrix least-squares to R=0.0528 for 2742 observed reflections in the first complex and by full-matrix least-squares to R=0.0252 for 1948 observed reflections in the second.In the octahedral ruthenium complex, DAP acts as a tridentate ligand adopting a mer configuration and the phosphine ligand is trans to the pyridinic nitrogen, while in the trans square-planar palladium complex DAP acts as a monodentate N-donor ligand.

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Reference：
Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI

In an article, published in an article, once mentioned the application of 246047-72-3, Name is (1,3-Bis(2,4,6-trimethylphenyl)-2-imidazolidinylidene)dichloro(phenylmethylene)(tricyclohexylphosphine)ruthenium,molecular formula is C46H65Cl2N2PRu, is a conventional compound. this article was the specific content is as follows.HPLC of Formula: C46H65Cl2N2PRu

An efficient, versatile and rapid method toward homologue series of lipophilic tetrapeptide derivatives (herein, the opioid peptides H-TIPP-OH and H-DIPP-OH) is reported. High atom economy and a minimal number of synthetic steps resulted from a one-pot tandem isomerization-cross metathesis-reduction sequence (ICMR), applicable both in solution and solid phase methodology. The broadly applicable synthesis proceeds with short reaction times and simple work-up, as illustrated in this work for alkylated opioid tetrapeptides.

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Reference：
Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI