The reaction rate of a catalyzed reaction is faster than the reaction rate of the uncatalyzed reaction at the same temperature.32993-05-8, Name is Chlorocyclopentadienylbis(triphenylphosphine)ruthenium(II), molecular formula is C41H35ClP2Ru. In a Article,once mentioned of 32993-05-8, Safety of Chlorocyclopentadienylbis(triphenylphosphine)ruthenium(II)
Structural determinations and electrochemical properties in the series of multinuclear ferrocenyl-ethynyl complexes with formula [(eta5-C5R5)(P2)MII-C{triple bond, long}C-(fc)n-C{triple bond, long}C-MII(P2)(eta5-C5R5)] (fc = ferrocenyl; M = Fe(II), Ru(II), Os(II); R = H, CH3; P2 = Ph2PCH2CH2PPh2 (dppe), (C2H5)2PCH2CH2P(C2H5)2 (depe)) are reported. Complexes with more electron-rich ligand environment, such as [M(eta5-C5R5)P2] (R = CH3 and P2 = dppe, depe), were also prepared with regard to the understanding of electronic coupling mechanism. Structural determinations confirm that the ferrocenyl group is directly linked to the ethynyl linkage which is linked to the pseudo-octahedral [(eta5-C5R5)(P2)M] metal center. These complexes undergo sequential reversible oxidation events from 0.0 to 1.0 V referred to the Ag/AgCl electrode in anhydrous CH2Cl2 solution and the low-potential waves have been assigned to the two end-capped metallic centers. The magnitude of the electronic coupling between the two terminal metallic centers in the series of complexes was estimated by the electrochemical technique. Based on the correlation between the DeltaE1/2 values and the second redox potentials of the end-capping metallic centers in the series of complexes, a qualitative explanation for the difference of the electronic coupling is given.
Note that a catalyst decreases the activation energy for both the forward and the reverse reactions and hence accelerates both the forward and the reverse reactions.Safety of Chlorocyclopentadienylbis(triphenylphosphine)ruthenium(II), you can also check out more blogs about32993-05-8
Reference:
Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI