Extracurricular laboratory:new discovery of Cis-Dichlorobis(2,2′-bipyridine)ruthenium(II)

Note that a catalyst decreases the activation energy for both the forward and the reverse reactions and hence accelerates both the forward and the reverse reactions.Computed Properties of C20H16Cl2N4Ru, you can also check out more blogs about15746-57-3

The reaction rate of a catalyzed reaction is faster than the reaction rate of the uncatalyzed reaction at the same temperature.15746-57-3, Name is Cis-Dichlorobis(2,2′-bipyridine)ruthenium(II), molecular formula is C20H16Cl2N4Ru. In a Article,once mentioned of 15746-57-3, Computed Properties of C20H16Cl2N4Ru

A conjugated polymer-redox polymer hybrid based on the complexation of poly[2-(2-pyridyl)bibenzimidazole] with bis(2,2′-bipyridyl)Ru2+ has been prepared to take advantage of electronic communication between metal centers through the conjugated backbone. The existence of such communication is confirmed by the observation of an intervalence charge-transfer band in the near-IR spectrum of the Ru(III/II) mixed valence state. Electron transport studies by rotating disk voltammetry, dual (sandwich) electrode voltammetry, and impedance spectroscopy have yielded electron diffusion coefficients (De) of over 10-8 cm2 s-1 for the Ru(III/II) mixed valence state. D(e) in nonconjugated Ru(2,2′-bipyridyl)3(3+/2+)-type polymers is typically less than this by at least a factor of 10, indicating that electron transport in the new polymer is enhanced by communication of metal centers through the backbone. The redox potential of the Ru sites, and D(e), can be manipulated by changing the electron density on the polymer backbone via pH control of the degree of protonation of the imidazole moieties.

Note that a catalyst decreases the activation energy for both the forward and the reverse reactions and hence accelerates both the forward and the reverse reactions.Computed Properties of C20H16Cl2N4Ru, you can also check out more blogs about15746-57-3

Reference:
Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI