New explortion of Chlorocyclopentadienylbis(triphenylphosphine)ruthenium(II)

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In an article, published in an article, once mentioned the application of 32993-05-8, Name is Chlorocyclopentadienylbis(triphenylphosphine)ruthenium(II),molecular formula is C41H35ClP2Ru, is a conventional compound. this article was the specific content is as follows.Computed Properties of C41H35ClP2Ru

The ruthenium chloride and hydride complexes Cp(PR3)2RuH {X = Cl; PR3 = PMe3 (1), PMe2Ph (2), PMePh2 (3), PPh3 (4); X = H; PR3 = PMe3 (5), PMe2Ph (6), PMePh2 (7), PPh3 (8)} were studied by spectroscopy and solution calorimetry. The structures of 2 and 3 are reported and complete the structural characterization of the series 1-4. In this series, the Ru-Cl distance (2.449 ± 0.007 A) remains constant, while the Ru-PR3 distance increases in the order 1 < 2 < 3 < 4. The ruthenium hydrides 5-8 were prepared from the reaction of the corresponding ruthenium chloride with KOMe in methanol. Do you like my blog? If you like, you can also browse other articles about this kind. Computed Properties of C41H35ClP2Ru. Thanks for taking the time to read the blog about 32993-05-8

Reference:
Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI