Synthetic Route of 10049-08-8, An article , which mentions 10049-08-8, molecular formula is Cl3Ru. The compound – Ruthenium(III) chloride played an important role in people’s production and life.
An interesting array of RuII complexes of the two NNS chelating ligands 2-(2-pyridyl)benzothiazoline (L1H) and its methyl analogue 2-methyl-2-(2-pyridyl) benzothiazoline (L2H) have been synthesized and characterized. Diverse coordination behaviour of the ligand (L1H) encompassing its (a) neutral bidentate, (b) monoacid tridentate and (c) monoacid bidentate character are amply illustrated in this study. However, L2H was found to behave only in the tridentate fashion. The complexes synthesized were of the type Ru2(L)2X2 [where L = L1, X = Cl (1); Br (2); and L = L2, X = Cl (6); Br (7)], trans and cis [Ru(L1H)2Cl2]·2H2O [(3) and (5)], [Ru(L1H)2(H2O)Cl]ClO4 (4) and Ru(L1)(L1H)Cl (8). Several mixed-ligand complexes containing substituted imidazoles and bipyridine were also isolated and in some of them the ligand is found to be coordinated as a neutral bidentate NS chelating agent. The chemical and electrochemical reactivity patterns of these complexes were explored. Plausible structural representation of the reported complexes are proposed from the analysis of spectroscopic and cyclic voltammetric data. Copyright
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Reference：
Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI