Application of 14564-35-3, Children learn through play, and they learn more than adults might expect. Science experiments are a great way to spark their curiosity, get their minds active, and encourage them to do something that doesn’t involve a screen. 14564-35-3, C38H34Cl2O2P2Ru. A document type is Article, introducing its new discovery.
Reaction of N-(2?-hydroxyphenyl)benzaldimines (abbreviated in general as H2L-R, where R stands for the para-substituent in the benzaldehyde fragment and H stands for the dissociable hydrogen atoms) with [Ru(PPh3)2(CO)2Cl2] affords a family of organoruthenium complexes of the type [Ru(PPh3)2(CO)(L-R)] where the N-(2?-hydroxyphenyl)benzaldimine ligand is coordinated to the metal center as tridentate C,N,O-donor. Structure of a representative complex has been determined by X-ray crystallography. All the [Ru(PPh3)2(CO)(L-R)] complexes are diamagnetic, and show characteristic 1H NMR signals and moderately intense MLCT transitions in the visible region. Cyclic voltammetry of the [Ru(PPh3)2(CO)(L-R)] complexes shows a reversible Ru(II)-Ru(III) oxidation within 0.38-0.68 V versus SCE, followed by an irreversible oxidation of the coordinated benzaldimine ligand within 1.09-1.27 V versus SCE. An irreversible reduction of the coordinated benzaldimine ligand is also observed near -1.1 V versus SCE. Potential of the Ru(II)-Ru(III) oxidation is observed to be sensitive to the nature of para-substituent R.
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Reference：
Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI