Application of 301224-40-8. Let’s face it, organic chemistry can seem difficult to learn. Especially from a beginner’s point of view. Like 301224-40-8, Name is (1,3-Dimesitylimidazolidin-2-ylidene)(2-isopropoxybenzylidene)ruthenium(VI) chloride. In a document type is Article, introducing its new discovery.
A monosilylated Hoveyda-Grubbs ruthenium alkylidene has been prepared and grafted through the NHC ligand to a mesostructured silica, in refluxing toluene or at room temperature, giving two new organic-inorganic hybrid silica materials M2 and M3, respectively. While M3 exhibited good performances in several metathesis reactions, M2 showed good selectivity in the hydrosilylation of terminal alkynes, where the beta-(Z)-vinylsilane was obtained as major product. Recycling of the supported catalysts without significant decrease in activity and selectivity was proven for at least three cycles in both transformations.
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Reference：
Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI