Reference of 32993-05-8, Children learn through play, and they learn more than adults might expect. Science experiments are a great way to spark their curiosity, get their minds active, and encourage them to do something that doesn’t involve a screen. 32993-05-8, C41H35ClP2Ru. A document type is Article, introducing its new discovery.
Reactions of {Cp(Ph3P)2Ru}2{mu-(C?C)n} (n = 3, 4) with C2(CN)4, dicobalt carbonyls and Fe2(CO)9 are described. For n = 3, the central C?C triple bond is attacked by the metal carbonyls, giving {Ru(PPh3)2Cp}2{mu-C?CC 2[Co2(CO)6]C?C} (4), {Ru(PPh3)2Cp}2{mu-C?CC 2[Co2(mu-dppm)(CO)4]C?C} (5) and Fe3{mu3-CC?C[Ru(PPh3)2Cp]} 2(CO)9 (7). For n = 4, the first bis-adduct with tcne is described, while the metal carbonyls gave {Ru(PPh3)2Cp}2{mu-C?CC 2[Co2(mu-dppm)(CO)4]C?CC?C} (6) and Fe3{mu3-CC?C[Ru(PPh3)2Cp]} {mu3-CC?CC?C[Ru(PPh3) 2Cp]}(CO)9 (8). While the usual bending of the carbon chain is found in the dicobalt complexes, reactions with the iron carbonyl result in cleavage of a C?C triple bond to give CFe3C clusters. The molecular structures of 4 and 7 have been determined.
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Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI