Children learn through play, and they learn more than adults might expect. Science experiments are a great way to spark their curiosity, get their minds active, and encourage them to do something that doesn’t involve a screen. 10049-08-8, Cl3Ru. A document type is Article, introducing its new discovery., SDS of cas: 10049-08-8
The nitrosation of [Ru(NH3)6]2+ in hydrochloric acid and alkaline ammonia media has been studied; the patterns of interconversion of ruthenium complexes in reaction solutions have been proposed. In both cases, nitrogen(II) oxide acts as the nitrosation agent. The procedure for the synthesis of [Ru(NO)(NH3)5]Cl3 ? H2O (yield 75-80%), the main nitrosation product of [Ru(NH 3)6]2+, has been optimized. Thermolysis of [Ru(NO)(NH3)5]Cl3 ? H2O in a helium atmosphere has been studied; the intermediates have been identified. One of these products is polyamidodichloronitrosoruthenium(II) whose subsequent decomposition gives an equimolar mixture of ruthenium metal and dioxide. The structure of trans-[RuNO(NH3)4Cl]Cl2, formed in the second stage of thermolysis and as a by-product in the nitrosation of [Ru(NH3)6]Cl2, has been determined by X-ray diffraction. Nauka/Interperiodica 2007.
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Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI