Discovery of Chlorocyclopentadienylbis(triphenylphosphine)ruthenium(II)

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Electric Literature of 32993-05-8. Let’s face it, organic chemistry can seem difficult to learn. Especially from a beginner’s point of view. Like 32993-05-8, Name is Chlorocyclopentadienylbis(triphenylphosphine)ruthenium(II). In a document type is Article, introducing its new discovery.

Cyclopentadienyl-bis(triphenylphosphine) carboxylatoruthenium(II) compounds, Ru(eta-C5H5)(PPh3)2(O2CR) have been prepared by reacting Ru(eta-C5H5)(PPh3)2Cl and AgO2CR in benzene.The 18-electron compounds are moderately stable and contain a unidentate carboxylato ligand.Cyclic voltammetry of these compounds shows the presence of a one-electron ruthenium(II)/ruthenium(III) couple near 0.6 V (vs SCE) in CH2Cl2.The half-wave potentials follow the Hammett linear free energy relationship when plotted against the ?-values of the substituents.

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Reference：
Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI