Sometimes chemists are able to propose two or more mechanisms that are consistent with the available data.name: Cis-Dichlorobis(2,2′-bipyridine)ruthenium(II), If a proposed mechanism predicts the wrong experimental rate law, however, the mechanism must be incorrect.Welcome to check out more blogs about 15746-57-3, in my other articles.
A catalyst don’t appear in the overall stoichiometry of the reaction it catalyzes, but it must appear in at least one of the elementary reactions in the mechanism for the catalyzed reaction. 15746-57-3, Name is Cis-Dichlorobis(2,2′-bipyridine)ruthenium(II), molecular formula is C20H16Cl2N4Ru. In a Article，once mentioned of 15746-57-3, name: Cis-Dichlorobis(2,2′-bipyridine)ruthenium(II)
The surface enhanced resonance Raman spectroscopy (SERRS) of a series of tris(2,2′-bipyridine)ruthenium(II) complexes on chemically produced silver films is reported.The SERR spectra of 2+, several tris complexes of Ru(II) containing substituted 2,2′-bipyridine (4,4′-dimethyl’, 4,4′-diphenyl-, 4,4′-diamino- and 4,4′-diethylcarboxylate-2,2′-bipyridine) ligands and the natural cis-bis complexes and show very high band intensities.The large enhancement arises from the combination of the inherent resonance Raman effect and the surface plasmon resonance (due to the rough nature of the silver film).The molecules are not chemisorbed on the silver surface and hence the enhancement occurs solely via the electromagnetic mechanism.The SERR spectra are virtually free of the fluorescence which dominates the corresponding RR spectra thus illustrating the use of SERRS in the vibrational spectroscopy of strongly luminescing species.The SERRS spectra of the substituted 2,2′-bipyridine complexes are discussed.
Sometimes chemists are able to propose two or more mechanisms that are consistent with the available data.name: Cis-Dichlorobis(2,2′-bipyridine)ruthenium(II), If a proposed mechanism predicts the wrong experimental rate law, however, the mechanism must be incorrect.Welcome to check out more blogs about 15746-57-3, in my other articles.
Reference：
Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI