37366-09-9, Name is Dichloro(benzene)ruthenium(II) dimer, molecular formula is C12H12Cl4Ru2, belongs to ruthenium-catalysts compound, is a common compound. In a patnet, once mentioned the new application about 37366-09-9, Formula: C12H12Cl4Ru2
The reactions of [{(eta6C6H6)RuCl(mu- Cl)}2] and [{(eta6-p-cymene)RuCl(mu,-Cl)}2] with N-[2-(arylchalcogeno)ethyl]morpholines (L) (aryl = Ph/2-pyridyl for S, Ph for Se, 4-MeOC6H4 for Te) and NH4PF6 result in “piano-stool” complexes of RuII of composition [RuCl(eta6-C6H6)/[eta6p-cymene) (L)][PF6], which give characteristic 1H, 13C[{1H}, 77Se[1H), and 125Te[1H] NMR spectra. Some of them have also been characterized by X-ray crystallography [Ru-S, Ru-Se, and Ru-Te bond lengths: 2.3815(12)/2.3742(14), 2.4837(14), and 2.6143(7) A, respectively]. The cyclic voltammograms show that all the complexes undergo irreversible oxidation (E1/2 = 0.290-0.586 V). All the ruthenium complexes have been explored for their catalytic activity in the oxidation of primary and secondary alcohols with N-methylmorpholine N-oxide (NMO), tBuOOH, NaOCl, and NaIO 4 (TON values upto 9.8 ×104). The efficiency of the catalytic oxidation reaction decreases in the order Te > Se > S. The intermediate species involved in the oxidation reactions appear to incorporate the RuIV=O group.
Balanced chemical reaction does not necessarily reveal either the individual elementary reactions by which a reaction occurs or its rate law.Formula: C12H12Cl4Ru2. In my other articles, you can also check out more blogs about 37366-09-9
Reference：
Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI