A catalyst don’t appear in the overall stoichiometry of the reaction it catalyzes, but it must appear in at least one of the elementary reactions in the mechanism for the catalyzed reaction. 37366-09-9, Name is Dichloro(benzene)ruthenium(II) dimer, molecular formula is C12H12Cl4Ru2. In a Article£¬once mentioned of 37366-09-9, Computed Properties of C12H12Cl4Ru2
Abstract Series of mononuclear complexes of arene Ru and Cp?Rh/Cp?Ir complexes containing (3-picolyl)thiourea derivative ligands, of general formulae [(eta6-arene)Ru(L)Cl]Cl and [Cp?M(L)Cl]Cl {L = benzoyl(3-picoylyl)thiourea, arene = benzene (1); p-cymene (2) and M = Rh (3); Ir (4); L = 1,3-bis(3-picolyl)thiourea, arene = benzene (5); p-cymene (6) and M = Rh (7); Ir (8)}, have been synthesized and characterized by spectroscopic methods. X-ray crystallographic studies of complexes (2)-(5), (7), and (8) reveal a typical piano-stool geometry around the metal center with a six-membered metallacycle, in which L acts as an N,S-chelating ligand. Intramolecular N-H¡¤¡¤¡¤S, S¡¤¡¤¡¤O, and N-H¡¤¡¤¡¤N interactions are found to play a significant role in the molecular structures.
Balanced chemical reaction does not necessarily reveal either the individual elementary reactions by which a reaction occurs or its rate law.Computed Properties of C12H12Cl4Ru2. In my other articles, you can also check out more blogs about 37366-09-9
Reference£º
Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI