In an article, published in an article, once mentioned the application of 32993-05-8, Name is Chlorocyclopentadienylbis(triphenylphosphine)ruthenium(II),molecular formula is C41H35ClP2Ru, is a conventional compound. this article was the specific content is as follows.HPLC of Formula: C41H35ClP2Ru
The rate dependence of the [Ru(eta5-C5H 5)(BIPHOP-F)(acetone)][Y] -catalyzed Diels-Alder reaction of cyclopentadiene with methacrolein on the anion, Y, is shown to be due to selective ion pairing. Pulsed gradient spin-echo (PGSE) diffusion measurements on the model Cp and indenyl complexes [Ru(eta5-C5H 5)(CH2=CH-CN)(BIPHOP-F)][Y], Y = BF4 and BArF, and [Ru(eta5-C9H7)(CH2=CH-CN) (BIPHOP-F)] [Y], Y = BF4 and BArF, respectively, combined with 1H-19F HOESY NMR data can be used to understand how the ion pairing for the BF4 anion differs relative to that of the BArF anion. Solid-state structures for [Ru(eta5-C5H 5)(CH2=CH-CN)(BIPHOP-F)][BF4] and [Ru(eta5-C5H5)(CH2=CH-CN)(BIPHOP- F)][BArF] are reported and support the NMR solution data. The model carbonyl complexes [Ru(eta5-C5H5)(BIPHOP-F)-(CO)][Y], 8 (Y = BF4, SbF6, and BArF) have been synthesized. The IR CO stretching frequencies for 8 showed little variation with anion, thereby proving that the anions do not affect the Lewis acidity of the salts.
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Reference£º
Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI