Final Thoughts on Chemistry for Dichlorodicarbonylbis(triphenylphosphine)ruthenium(II)

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Related Products of 14564-35-3, An article , which mentions 14564-35-3, molecular formula is C38H34Cl2O2P2Ru. The compound – Dichlorodicarbonylbis(triphenylphosphine)ruthenium(II) played an important role in people’s production and life.

The complex <(OC)4Re(OH2)2>+ reacts with oxalate and squarate to give the complexes <(OC)4Re(OH2)2>C2O4 (1) and <(OC)4Re(OH2)2>C4O4 (2).The reaction of (OC)2(PPh3)2Ru(FBF3)2 with potassium salts of alpha-aminoacids (glycine, L-alanine, L-phenylalanine) yields cationic ruthenium complexes with chelating aminoacidates (3-5).With acetylacetonate the complex <(OC)2(PPh3)2Ru(acac)> (16) is obtained.Nitriles and isonitriles give the complexes <(OC)4Re(N<*>C-R)2> (6: R=Me; 7: R=CH2CO2Et), <(OC)2(PPh3)2Ru(N<*>C-R)2>2 (8: R=Me, 9: R=p-C6H4OMe), <(OC)4Re(C<*>N-R)2> (10: R=(CH2)3Me; 11: R=CH2CO2Et) and <(OC)2(PPh3)2Ru(C<*>N-R)2>2 (12: R=CH2CO2Et; 13: R=C6H11), respectively.With thioethers (OC)4Re(OEt2)FBF3 forms the complexes <(OC)4Re(Ph-S-CH2-S-Ph)> (14) and <(OC)4Re(HO-(CH2)2-S-(CH2)2-S-(CH2)2OH)> (15). Key words: Ruthenium; Rhenium; Phosphorus; Tetrafluoroborate

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Reference：
Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI