A catalyst don’t appear in the overall stoichiometry of the reaction it catalyzes, but it must appear in at least one of the elementary reactions in the mechanism for the catalyzed reaction. 14564-35-3, Name is Dichlorodicarbonylbis(triphenylphosphine)ruthenium(II), molecular formula is C38H34Cl2O2P2Ru. In a Article，once mentioned of 14564-35-3, Safety of Dichlorodicarbonylbis(triphenylphosphine)ruthenium(II)
The hydrogenation of myrcene catalyzed by Ru, Cr, Ir and Rh complexes leads to the formation of a complex mixture of mono-, di- and trihydrogenated products. Seven major products have been characterized, showing that they arise from the sigma-alkyl and/or eta3-allyl intermediates formed by the reaction of metal catalysts with both terminal CC bonds of myrcene. A good control of chemoselectivity has been achieved through the appropriate choice of the metal and reaction conditions. Monohydrogenated products have been obtained with excellent combined selectivity of 95-98% at a high conversion of myrcene (>80%). Among the catalysts studied, rhodium complexes show the highest activity and selectivity, especially at temperatures lower than 100 C.
Sometimes chemists are able to propose two or more mechanisms that are consistent with the available data.Safety of Dichlorodicarbonylbis(triphenylphosphine)ruthenium(II), If a proposed mechanism predicts the wrong experimental rate law, however, the mechanism must be incorrect.Welcome to check out more blogs about 14564-35-3, in my other articles.
Reference：
Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI