A new application about Ruthenium(III) chloride

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In an article, published in an article, once mentioned the application of 10049-08-8, Name is Ruthenium(III) chloride,molecular formula is Cl3Ru, is a conventional compound. this article was the specific content is as follows.Recommanded Product: 10049-08-8

The development of green, selective, and efficient catalysts, which can aerobically oxidize a variety of alcohols to their corresponding aldehydes and ketones, is of both economic and environmental significance. We report here the synthesis of a novel aerobic oxidation catalyst, a zeolite-confined nanometersized RuO2 (RuO2-FAU), by a one-step hydrothermal method. Using the spatial constraints of the rigid zeolitic framework, we sucessfully incorporated RuO2 nanoparticles (1.3 ± 0.2 nm) into the supercages of faujasite zeolite. Ru K-edge X-ray absorption fine structure results indicate that the RuO2 nanoclusters anchored in the zeolite are structurally similar to highly hydrous RuO2; that is, there is a two-dimensional structure of independent chains, in which RuO6 octahedra are connected together by two shared oxygen atoms. In our preliminary catalytic studies, we find that the RuO2 nanoclusters exhibit extraordinarily high activity and selectivity in the aerobic oxidation of alcohols under mild conditions, for example, air and ambient pressure. The physically trapped RuO2 nanoclusters cannot diffuse out of the relatively narrow channels/pores of the zeolite during the catalytic process, making the catalyst both stable and reusable.

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Reference:
Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI