Reference of 37366-09-9, Children learn through play, and they learn more than adults might expect. Science experiments are a great way to spark their curiosity, get their minds active, and encourage them to do something that doesn’t involve a screen. 37366-09-9, C12H12Cl4Ru2. A document type is Article, introducing its new discovery.
The whole “pybox” and dice: Highly enantioselective amination reactions of both allylic and benzylic C-H bonds are catalyzed by cationic ruthenium(II)-pybox complexes (see structure). A novel mode of stereocontrol, which is induced by the versatile pybox ligand, is proposed to account for the excellent enantioselectivity in these reactions. Boc = tert-butoxycarbonyl, pybox = pyridine bisoxazoline. (Chemical Equation Presented)
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Reference：
Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI