Reference of 32993-05-8, Children learn through play, and they learn more than adults might expect. Science experiments are a great way to spark their curiosity, get their minds active, and encourage them to do something that doesn’t involve a screen. 32993-05-8, C41H35ClP2Ru. A document type is Article, introducing its new discovery.
This paper describes the successful preparation of new Ru(IV)-pi-allyl complexes having the general formula (C5R5)RuX2(eta3-allyl) (R = H, Me; X = Cl, Br) by the oxidative addition of allylic halides to Ru(II) complexes, (C5R5)Ru(L)2X (R = H, Me; L = CO, PPh3; X = Br, Cl). These new compounds were subjected to NMR analysis to determine the structure, which was confirmed by X-ray crystallographic analysis of a representative compound. During the course of this study, the authors found facile reductive elimination of allylic halides from the Ru(IV)-pi-allyl complexes to form Ru(II)-carbonyl or Ru(II)-arene complexes, induced by contact with CO or aromatic solvents, respectively.
If you are hungry for even more, make sure to check my other article about 32993-05-8. Reference of 32993-05-8
Reference：
Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI