32993-05-8, Name is Chlorocyclopentadienylbis(triphenylphosphine)ruthenium(II), molecular formula is C41H35ClP2Ru, belongs to ruthenium-catalysts compound, is a common compound. In a patnet, once mentioned the new application about 32993-05-8, Application In Synthesis of Chlorocyclopentadienylbis(triphenylphosphine)ruthenium(II)
(eta5-Cyclopentadienyl)(eta5-ligand)ruthenium(II) (ligand=1,2,3,4,5-eta6-exo-methoxy-d3-7-oxo-2,4-cycloheptadienyl-2d 3a, 1,2,3,4,5-eta6-exo-methoxy-7-oxo-2,4-cycloheptadienyl-2d, 1,2,3,4,5-eta6-exo-methoxy-7-oxo-2,4-cycloheptadienyl, and 1,2,3,4,5-eta6-exo-ethoxy-7-oxo-2,4-cycloheptadienyl) was isolated in fairly good yields by treatment of (eta5-C5H5)(eta6-tropone)ruthenium(II)BF4 with KOH in CD3OD, CH3OD, CH3OH, and ethanol, respectively. The selectively deuterated tropone-2d was readily removed by photolysis of 3a accompanied by demethoxylation with visible light in the presence of large excess of P(OCH3)3.
Balanced chemical reaction does not necessarily reveal either the individual elementary reactions by which a reaction occurs or its rate law.Application In Synthesis of Chlorocyclopentadienylbis(triphenylphosphine)ruthenium(II). In my other articles, you can also check out more blogs about 32993-05-8
Reference：
Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI