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Exchange of tertiary phosphites for PPh3 in RuCl(PPh3)2(eta-C5H5) afforded RuCl2(eta-C5H5) (R3=Me3, (CH2CF3)3, (CH2)3CEt).Conventional reactions of the P(OMe)3 complex afforded RuX2(eta-C5H5) (X=H, C(CO2Me)=CH(CO2Me), SnCl3, C2Ph, <*>C=CPhC(CN)2C<*>(CN)2, C<=C(CN)2>CPh=C(CN)2 (red and yellow forms)) or 2(eta-C5H5)>+ 2(eta-C5H5) are orthorhombic, space group Pna21 with unit cell dimensions a 9.606(3), b 14.167(4) and c 12.891(4) Angstroem and Z=4; RuCPh=C(CN)2>2(eta-C5H5) exists as two isomers: yellow form, triclinic, space group PI, a 9.496(6), b 10.436(6), c 15.216(2) Angstroem, alpha 90.74(2), beta 90.22(3), gamma 111.47(4) deg and Z=2; red form, orthorhombic, space group Pbca, a 14.501(5), b 15.047(2), c 26.658(4) Angstroem and Z=4.The structures were each refined by a full-matrix least-squares procedure to final R=0.051, Rw=0.050 for 1419 reflections with I>2.5?(I) for RuCl2(eta-C5H5); R=0.037, Rw=0.041 for 2930 reflections for the yellow isomer of RuCPh=C(CN)2>2(eta-C5H5); and R=0.033, Rw=0.035 for 1661 reflections for the red isomer.
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Reference：
Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI