Reference of 10049-08-8. Let’s face it, organic chemistry can seem difficult to learn. Especially from a beginner’s point of view. Like 10049-08-8, Name is Ruthenium(III) chloride. In a document type is Article, introducing its new discovery.
We describe the synthesis of two homo- and dinuclear complexes containing hexameric methylcycloarsoxane as ligand. The reaction of (MeAsO)n with RhCl3 results in the formation of [(RhCl3) 2{cyclo-(MeAsO)6}] (1), the reaction with RhBr3 in the formation of [(RhBr3)2{cyclo-(MeAsO)6}] (2). Small changes in the reaction temperature lead to the formation of the related mononuclear complex [RhBr3{cyclo-(MeAsO)6}] (3). We were also able to synthesis and characterise a hetero- and dinuclear complex [(RuCl3)(PdCl2) {cyclo-(Me6As6O 7)}] (4a) and [(RhCl3KPdCl2)-{cyclo-(MeAsO) 6}] (4b) respectively, the first example of a methylcycloarsoxan coordinating two different transition metal atoms with different coordination spheres.
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Reference：
Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI