In an article, published in an article, once mentioned the application of 14564-35-3, Name is Dichlorodicarbonylbis(triphenylphosphine)ruthenium(II),molecular formula is C38H34Cl2O2P2Ru, is a conventional compound. this article was the specific content is as follows.Product Details of 14564-35-3
Alcohols are oxidized by N-methylmorpholine-N-oxide (NMO), Bu tOOH and H2O2 to the corresponding aldehydes or ketones in the presence of catalyst, [RuH(CO)(PPh3) 2(SRaaiNR)]PF6 (2) and [RuCl(CO)(PPh3)(S kappaRaaiNR)]PF6 (3) (SRaaiNR (1) = 1-alkyl-2-{(o- thioalkyl)phenylazo}imidazole, a bidentate N(imidazolyl) (N), N(azo) (N) chelator and SkappaRaaiNR is a tridentate N(imidazolyl) (N), N(azo) (N), Skappa-R is tridentate chelator; R and R are Me and Et). The single-crystal X-ray structures of [RuH(CO)(PPh3) 2(SMeaaiNMe)]PF6 (2a) (SMeaaiNMe = 1-methyl-2-{(o- thioethyl)phenylazo}imidazole) and [RuH(CO)(PPh3) 2(SEtaaiNEt)]PF6 (2b) (SEtaaiNEt = 1-ethyl-2-{(o- thioethyl)phenylazo}imidazole) show bidentate N,N chelation, while in [RuCl(CO)(PPh3)(SkappaEtaaiNEt)]PF6 (3b) the ligand SkappaEtaaiNEt serves as tridentate N,N,S chelator. The cyclic voltammogram shows RuIII/RuII (~1.1 V) and Ru IV/RuIII (~1.7 V) couples of the complexes 2 while Ru III/RuII (1.26 V) couple is observed only in 3 along with azo reductions in the potential window +2.0 to -2.0 V. DFT computation has been used to explain the spectra and redox properties of the complexes. In the oxidation reaction NMO acts as best oxidant and [RuCl(CO)(PPh 3)(SkappaRaaiNR)](PF6) (3) is the best catalyst. The formation of high-valent RuIV=O species as a catalytic intermediate is proposed for the oxidation process. Copyright
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Reference：
Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI