Synthetic Route of 20759-14-2. Chemistry is an experimental science, and the best way to enjoy it and learn about it is performing experiments.Introducing a new discovery about 20759-14-2, Name is Ruthenium(III) chloride hydrate
The complexes RuCl3(CTZ)3·2CH3OH (1) and RuCl3(KTZ)2(H2O)·2H2O (2) were prepared by reaction of RuCl3·3H2O with CTZ and KTZ, respectively, while RuCl2(KTZ)2 (4) was prepared by reaction of RuCl2(CH3CN)4 with KTZ (CTZ = 1-[(2-chlorophenyl)diphenylmethyl-1H-imidazole, and KTZ = cis-1-acetyl-4-[4-[[2-(2,4-dichlorophenyl)-2-(1H-imidazol-1-ylmethyl)-1,3-dio xolan-4-yl]methoxy]phenyl]piperazine. All the complexes were characterized by NMR spectroscopy and for the paramagnetic species EPR spectroscopy was also employed. The new compounds were tested for in vitro activity against cultures of epimastigotes of Trypanosoma cruzi, the causative agent of Chagas disease, and compared with RuCl2(CTZ)2 (3) (reported previously) in order to establish some structure-activity correlations. At concentrations of 10-6 M (DMSO), all the complexes showed higher activity than the parental organic drug against the epimastigote form of the parasite, and Ru(II) complexes seem to be more active than their Ru(III) counterparts for a given nitrogen-donor ligand.
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Reference：
Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI