Synthetic Route of 246047-72-3. Let’s face it, organic chemistry can seem difficult to learn. Especially from a beginner’s point of view. Like 246047-72-3, Name is (1,3-Bis(2,4,6-trimethylphenyl)-2-imidazolidinylidene)dichloro(phenylmethylene)(tricyclohexylphosphine)ruthenium. In a document type is Article, introducing its new discovery.
The total synthesis of gravicycle, isolated from Grevillea robusta, has been achieved for the first time. The key step of our synthetic process is the efficient assembly of a highly functionalized biaryl ether via the copper-catalyzed O-arylation of suitably protected pyrogallol-5-carboxylate, using triarylbismuth( V) diacetate.
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Reference：
Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI