Extracurricular laboratory:new discovery of 37366-09-9

Note that a catalyst decreases the activation energy for both the forward and the reverse reactions and hence accelerates both the forward and the reverse reactions.Computed Properties of C12H12Cl4Ru2, you can also check out more blogs about37366-09-9

The reaction rate of a catalyzed reaction is faster than the reaction rate of the uncatalyzed reaction at the same temperature.37366-09-9, Name is Dichloro(benzene)ruthenium(II) dimer, molecular formula is C12H12Cl4Ru2. In a Review，once mentioned of 37366-09-9, Computed Properties of C12H12Cl4Ru2

Ruthenium(II) dimers [{Ru(eta6-arene)(mu-Cl) Cl}2] (1a-f) readily react with the iminophosphorane-phosphine ligand Ph2PCH2P(=N-p-C5F4N) Ph2 (2), in dichloromethane at room temperature, to afford the neutral derivatives [Ru(eta6-arene)Cl2 {k1-PPh2PCH2P(=N-p-C5 F4N)Ph2}](arene=C6H6 (3a), 1-iPr-4-C6H4Me (3b), 1,3,5-C6H3Me3 (3c),1,2,3,4- C6H2Me4 (3d), 1,2,4,5-C6 H2Me4 (3e), C6Me6 (3f)). Treatment of 3a-f with AgSbF6 in dichloromethane yields the cationic species [Ru(eta6-arene) Cl{k2-P,N-Ph2 PCH2P(=N-p-C5F4N)Ph2}][SbF6] (4a-f). The catalytic activity of complexes 3 and 4 in transfer hydrogenation of cyclohexanone by propan-2-ol has been studied. Among them, the cationic derivative [Ru(eta6-C6Me6)Cl{k2-P, N-Ph2PCH2P(= N-p-C5F4N) Ph2}][SbF6] (4f) shows the highest activity. Electrochemical data for 3 and 4 are also reported.

Note that a catalyst decreases the activation energy for both the forward and the reverse reactions and hence accelerates both the forward and the reverse reactions.Computed Properties of C12H12Cl4Ru2, you can also check out more blogs about37366-09-9

Reference：
Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI