A catalyst don’t appear in the overall stoichiometry of the reaction it catalyzes, but it must appear in at least one of the elementary reactions in the mechanism for the catalyzed reaction. 37366-09-9, Name is Dichloro(benzene)ruthenium(II) dimer, molecular formula is C12H12Cl4Ru2. In a Article，once mentioned of 37366-09-9, Product Details of 37366-09-9
Compounds derived from the reactions of dimeric arene ruthenium [{(eta6-arene)Ru(mu-Cl)Cl}2] (arene = benzene and p-cymene) and structurally analogous rhodium and iridium complexes [{(eta5-C5Me5)M(mu-Cl)Cl}2] (M = Rh or Ir) with 2-chloro-4,6-(di-2-pyridylamino)-1,3,5-triazine (cddt) and 2,4,6-tris(di-2-pyridylamino)-1,3,5-triazine (tdat) are reported. Compounds under investigation have been characterized by elemental analyses, NMR ( 1H and 13C), electronic absorption, emission spectral and electrochemical studies. Structures of the dinuclear compounds [{(eta6-C10H14)RuCl}2(cddt)] (PF6)2, [{(eta5-C5Me 5)RhCl}2(cddt)]Cl2·6H2O and trinuclear compound [{(eta6-C6H6)RuCl} 3(tdat)]Cl3·4H2O have been determined crystallographically. Among cddt containing compounds the {(eta6- C10H14)RuCl}- units in [{(eta6-C 10H14)RuCl}2(cddt)](PF6) 2 are anti, while {(eta5-C5Me 5)RhCl}- in the rhodium compound [{(eta5-C 5Me5)RhCl}2(cddt)]Cl2·6H 2O are syn with respect to triazine ring. Cyclic voltammetric studies on the compounds suggested lack of communication between the metal centres. Furthermore, although tdat is luminescent at room temperature compounds under investigation containing this ligand are non-luminescent in acetonitrile. Compounds derived from the reactions of dimeric arene ruthenium [{(eta6-arene)Ru(mu-Cl)Cl}2] (arene = benzene and p-cymene) and structurally analogous rhodium and iridium complexes [{(eta5-C5Me5)M(mu-Cl)Cl}2] (M = Rh or Ir) with 2-chloro-4,6-(di-2-pyridylamino)-1,3,5-triazine (cddt) and 2,4,6-tris(di-2-pyridylamino)-1,3,5-triazine (tdat) are described. Compounds under study have been fully characterized by analytical, spectral and electrochemical studies and structures of [{(eta6-C 10H14)RuCl}2(cddt)](PF6) 2, [{(eta5-C5Me5)RhCl} 2(cddt)]Cl2·6H2O, and [{(eta6-C6H6)RuCl}3(tdat)]Cl 3·4H2O have been authenticated crystallographically.
Balanced chemical reaction does not necessarily reveal either the individual elementary reactions by which a reaction occurs or its rate law.Product Details of 37366-09-9. In my other articles, you can also check out more blogs about 37366-09-9
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Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI