Related Products of 32993-05-8, Chemistry can be defined as the study of matter and the changes it undergoes. You’ll sometimes hear it called the central science because it is the connection between physics and all the other sciences, starting with biology.32993-05-8, Name is Chlorocyclopentadienylbis(triphenylphosphine)ruthenium(II), molecular formula is C41H35ClP2Ru. In a patent, introducing its new discovery.
This paper reports preparation of new silyl hydride complexes of ruthenium supported by the Cp/PR3 ligand set. It is shown that the easiest and most general route to these complexes is provided by the thermal reaction of [RuCp(PR3)(H)3] with hydrosilanes. Complexes [RuCp(PR 3)(H)2(SiMe2Cl)] exhibit Interligand Hypervalent Interactions (IHI) between the hydride and silyl ligands. Comparison of the X-ray structures of complexes [RuCp(PPri3)(H) 2(SiMe2Cl)], [RuCp(PPhPri2)(H) 2(SiMe2Cl)], and [RuCp(PPh3)(H) 2(SiMe2Cl)] shows that the IHI weakens with the decreasing electron-releasing ability of the phosphine. Comparison of the X-ray structure of [RuCp(PPh3)(H)2(SiMe2Cl)] with the structure of the previously reported complex [RuCp*(PPh3)(H) 2(SiMe2Cl)] reveals that the lack of IHI in the latter compound is due to unfavourable steric interactions between the bulkier Cp* ring and the SiMe2Cl group.
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Reference：
Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI