10049-08-8, Name is Ruthenium(III) chloride, molecular formula is Cl3Ru, belongs to ruthenium-catalysts compound, is a common compound. In a patnet, once mentioned the new application about 10049-08-8, Product Details of 10049-08-8
Treatment of RuCl2(PPh3)3 with HC?CCH(OH)C?CH/PPh3 at room temperature produces the air-stable ruthenabenzene [Ru(CHC(PPh3)CHC(PPh3)CH)Cl 2(PPh3)2]Cl (2) in good yield. The ruthenabenzene 2 can even be obtained from the one-pot reaction of RuCl 3, PPh3, and HC?CCH(OH)C?CH in the mixed solvent of ionic liquid and CH2Cl2 in higher yield. The ruthenabenzene 2 reacts with PMe3, PBu3, tert-butyl isocyanide, 2,2?-dipyridyl (bipy), and 2,2?-dipyridyl/PMe 3 to give new stable ruthenabenzenes [Ru(CHC(PPh3) CHC(PPh3)CH)Cl2(PMe3)2]Cl (4), [Ru(CHC(PPh3)CHC(PPh3)CH)Cl2(PBu 3)2]Cl (5), [Ru(CHC(PPh3)CHC(PPh 3)CH)Cl(tBuNC)(PPh3)2]Cl 2 (6), [Ru(CHC(PPh3)CHC(PPh3)CH)Cl(bipy) (PPh3)]Cl2 (7), and [Ru(CHC(PPh3)CHC(PPh 3)CH)(bipy)(PMe3)2]Cl3 (8), respectively. Reaction of ruthenabenzene 2 with AgBF4 gives bisruthenabenzene [Ru(CHC(PPh3)CHC(PPh3)CH)(PPh 3)]2(mu-Cl)3(BF4)3 (9). The thermal decomposition reactions of ruthenabenzene 2 and 7 produce a stable Cp- ion derivative, [CHC(PPh3)CHC(PPh3)CH]Cl (10). 2, 4, 7, 8, 9, and 10 have been structurally characterized. 9 is the first non-metal-coordinated bismetallabenzene. An electrochemical study shows that the metal centers in the bisruthenabenzene 9 slightly interact with each other through the chloro bridges.
Balanced chemical reaction does not necessarily reveal either the individual elementary reactions by which a reaction occurs or its rate law.Product Details of 10049-08-8. In my other articles, you can also check out more blogs about 10049-08-8
Reference：
Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI