Electric Literature of 37366-09-9, An article , which mentions 37366-09-9, molecular formula is C12H12Cl4Ru2. The compound – Dichloro(benzene)ruthenium(II) dimer played an important role in people’s production and life.
Stable dinuclear transition metal complexes,[(I·6- C6H6)2Ru2(L1)Cl2] 2+ (1), [(I·6-p-iPrC6H 4Me)2Ru2(L1)Cl2]2+ (2), [(I·6-C6Me6)2Ru 2(L1)Cl2]2+ (3), [(I·6- C6H6)2Ru2(L2)Cl2] 2+ (4),[(I·6-p-iPrC6H 4Me)2Ru2(L2)Cl2]2+ (5), [(I·6-C6Me6)2Ru 2(L2)Cl2]2+ (6), [(I·5- C5Me5)2Rh2(L1)Cl2] 2+ (7), [(I·5-C5Me 5)2Ir2(L1)Cl2]2+ (8),[(I·5-C5Me5) 2Rh2(L2)Cl2]2+ (9), and [(I·5-C5Me5)2Rh 2(L2)Cl2]2+ (10), with the bis-bidentate ligands 1,3-bis(di-2-pyridylaminomethyl)benzene (L1) and 1,4-bis(di-2- pyridylaminomethyl)benzene (L2), which contain two chelating dipyridylamine units connected by an aromatic spacer, were synthesized. The cationic dinuclear complexes were isolated as their hexafluorophosphate salts and characterized by using a combination of NMR, IR, and UV/Vis spectroscopic methods and mass spectrometry. The solid-state structure of complex 8 as a representative was determined by X-ray structure analysis. Copyright
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Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI