Related Products of 32993-05-8. Let’s face it, organic chemistry can seem difficult to learn. Especially from a beginner’s point of view. Like 32993-05-8, Name is Chlorocyclopentadienylbis(triphenylphosphine)ruthenium(II). In a document type is Article, introducing its new discovery.
The reaction of the halocarbyne [W(?CBr)(CO)2(Tp*)] (Tp=hydrotris(3,5-dimethylpyrazol-1-yl)borate) with trimethylsilyl-butadiyne, mediated by [Pd(PPh3)4] and CuI, affords the first pentadiynylidyne complex [W(?CC?CC?CSiMe3)(CO)2(Tp*)]. Desilylation provides a general route to heterobimetallic pentacarbido complexes, including [(Tp*)(CO)2W(mu-C5)(PPh3)2Ru(eta-C5H5)] and [(Ph3P)2(CO)HIr{(mu-C5)W(CO)2(Tp*)}2].
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Reference：
Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI