If you are hungry for even more, make sure to check my other article about 20759-14-2. Application of 20759-14-2
Application of 20759-14-2. Chemistry is an experimental science, and the best way to enjoy it and learn about it is performing experiments.Introducing a new discovery about 20759-14-2, Name is Ruthenium(III) chloride hydrate
Osmium(IV) dithioether complexes have been prepared from the ligands and sodium hexachloro-osmate(IV); (L’=MeS(CH2)2SMe or MeSCH=CHSMe) are formed from K2.Iridium(III) anions, , cis and trans-, , and 2, are oxidized by chlorine to the corresponding iridium(IV) complexes.Halogen oxidation of produces (X = Cl or Br) and two unstable complexes .Attempts to prepare thioether complexes of RuIV, RhIV, PdIV, CoIII and NiIII have been unsuccessful .The isolated complexes have been characterized by i.r. and electronic spectroscopy, and where appropriate magnetic measurements and 1H n.m.r. spectroscopy.Variable-temperature 1H n.m.r. spectra show that inversion at sulphur co-ordinated to PtIV is more difficult than in the platinum(II) analogues.Thermal decomposition of (X = Cl,Br, or I) involves both dehalogenation and dealkylation.
If you are hungry for even more, make sure to check my other article about 20759-14-2. Application of 20759-14-2
Reference：
Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI