A catalyst don’t appear in the overall stoichiometry of the reaction it catalyzes, but it must appear in at least one of the elementary reactions in the mechanism for the catalyzed reaction. 37366-09-9, Name is Dichloro(benzene)ruthenium(II) dimer, molecular formula is C12H12Cl4Ru2. In a Article，once mentioned of 37366-09-9, Application In Synthesis of Dichloro(benzene)ruthenium(II) dimer
Homo-hetero binuclear cationic complexes with the formulation [(eta 6-arene)RuCl(mu-dpp)(L)]+ (eta6-arene = benzene; L = PdCl2 (1a); PtCl2 (1b), and eta 6-arene = p-cymene; L = PdCl2 (2a); PtCl2 (2b)), [(eta6-arene)RuCl(mu-dpp)(L)]2+(eta 6-arene = p-cymene; L = [(eta6-C6H 6)RuCl] (2c), and [(eta6-C10H 14)RuCl] (2d)) were prepared. Molecular structure of the representative homo binuclear complex [{(eta6-C10H 14)RuCl}(mu-dpp){(eta6-C10H 14)RuCl}](PF6)2 (2d) was determined crystallographically. Weak interaction studies on the complex 2d revealed stabilisation of the crystal packing by weak inter and intra molecular C-H?X (X = F, Cl, pi) and pi-pi interactions. The C-H?F interactions lead to parallel helical chains and encapsulation of counter anion in self-assembled cavity arising from C-H?pi and pi-pi weak interactions.
Sometimes chemists are able to propose two or more mechanisms that are consistent with the available data.Application In Synthesis of Dichloro(benzene)ruthenium(II) dimer, If a proposed mechanism predicts the wrong experimental rate law, however, the mechanism must be incorrect.Welcome to check out more blogs about 37366-09-9, in my other articles.
Reference：
Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI