Synthetic Route of 10049-08-8. Let¡¯s face it, organic chemistry can seem difficult to learn. Especially from a beginner¡¯s point of view. Like 10049-08-8, Name is Ruthenium(III) chloride. In a document type is Article, introducing its new discovery.
Sensitized photoisomerization of cis-stilbazolium ions intercalated in saponite clay layers
Sensitized photoisomerization of the cis-stilbazolium ion 1 by ruthenium tris-2,2?-bipyridine [Ru(bpy)32+] was studied in saponite clay layers. The reaction yield was 100 times higher than the reaction yield in a homogeneous solution. The Stern-Volmer constant of the luminescence of Ru(bpy)32+ by 1 was 3.4 ¡Á 105 dm3 mol-1, which made the quenching rate constant faster than the diffusion limiting rate. The fast quenching rate implies a static quenching by 1 in the vicinity of Ru(bpy)32+. The reaction efficiency showed a maximum when 70 mol% of 1 was intercalated on the basis of the cation exchange capacity (CEC), where the ruthenium complex and 1 are suitably arranged in the saponite layer for effective photoelectron transfer and subsequent electron relay.
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Reference£º
Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI