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Related Products of 10049-08-8. Let¡¯s face it, organic chemistry can seem difficult to learn. Especially from a beginner¡¯s point of view. Like 10049-08-8, Name is Ruthenium(III) chloride. In a document type is Article, introducing its new discovery.
Preparation and Structure of Tetraphenylphosphonium Aquatetrachlorothionitrosylruthenate,
The preparation and structural characterization of are reported.Reaction of S3N3Cl3 with ruthenium trichloride yielded a brown crude product .The salt was prepared by the addition of PPh4Cl to an aqueous solution of followed by recrystallization of the brown precipitate from water-methanol (1:1).The crystals are triclinic, space group <*>, with unit-cell dimensions a = 10.173(5), b = 11.756(4), c = 12.793(10) Angstroem, alpha = 66.24(6), beta = 78.89(6), gamma = 72.58(4) deg, and Z = 2 (110 +/- 2K).The – anion forms an octahedron with H2O trans to the thionitrosyl group.The Ru-N-S group is approximately linear <170.9(3) deg> with Ru-N and N-S bond distances of 1.729(4) and 1.504(4) Angstroem, respectively.
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Reference£º
Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI