Extracurricular laboratory:new discovery of 37366-09-9

Balanced chemical reaction does not necessarily reveal either the individual elementary reactions by which a reaction occurs or its rate law.category: ruthenium-catalysts. In my other articles, you can also check out more blogs about 37366-09-9

37366-09-9, Name is Dichloro(benzene)ruthenium(II) dimer, molecular formula is C12H12Cl4Ru2, belongs to ruthenium-catalysts compound, is a common compound. In a patnet, once mentioned the new application about 37366-09-9, category: ruthenium-catalysts

Water-soluble ruthenium(II) catalysts [RuCl2(eta6- arene)-{P(CH2OH)3}] for isomerization of allylic alcohols and alkyne hydration

The novel water-soluble ruthenium(II) complexes [RuCl 2(eta6-arene){P(CH2OH)3}] 2a-c and [RuCl(eta6-arene){P(CH2OH)3} 2][Cl] 3a-c have been prepared in high yields by reaction of dimers [{Ru(eta6-arene)(mu-Cl)Cl}2] (arene = C 6H6 1a, p-cymene 1b, C6Me6 1c) with two or four equivalents of P(CH2OH)3, respectively. Complexes 2/3a-c are active catalysts in the redox isomerization of several allylic alcohols into the corresponding saturated carbonyl compounds under water/n-heptane biphasic conditions. Among them, the neutral derivatives [RuCl2(eta6-C6H6){P(CH 2OH)3}] 2a and [RuCl2(eta6-p- cymene){P(CH2OH)3}] 2b show the highest activities (TOP values up to 600 h-1; TON values up to 782). Complexes 2/3a-c also catalyze the hydration of terminal alkynes.

Balanced chemical reaction does not necessarily reveal either the individual elementary reactions by which a reaction occurs or its rate law.category: ruthenium-catalysts. In my other articles, you can also check out more blogs about 37366-09-9

Reference£º
Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI