The reaction rate of a catalyzed reaction is faster than the reaction rate of the uncatalyzed reaction at the same temperature.37366-09-9, Name is Dichloro(benzene)ruthenium(II) dimer, molecular formula is C12H12Cl4Ru2. In a Article£¬once mentioned of 37366-09-9, SDS of cas: 37366-09-9
Arene-ruthenium complexes with phosphanylferrocenecarboxamides bearing polar hydroxyalkyl groups-synthesis, molecular structure, and catalytic use in redox isomerizations of allylic alcohols to carbonyl compounds
Phosphanylferrocenecarboxamide Ph2P-fc-CONHCH2CH 2OH (1, fc = ferrocene-1,1?-diyl) and its newly synthesized congeners, Ph2P-fc-CONHCH(CH2OH)2 (2) and Ph2P-fc-CONHC(CH2OH)3 (3), were converted to a series of (eta6-arene)ruthenium complexes [(eta6- arene)RuCl2(L-kappaP)] 5-7, where arene is benzene, p-cymene, and hexamethylbenzene and L = 1-3. All compounds were characterized by multinuclear NMR and IR spectroscopy, by mass spectrometry, and by elemental analysis. The molecular structures of 2, 3, 3O (a phosphane oxide resulting from the oxidation of 3), 5c¡¤CH2Cl2, and 6c¡¤Et2O were determined by single-crystal X-ray diffraction analysis. The ruthenium complexes were further evaluated as catalysts in the redox isomerization of allyl alcohols to carbonyl compounds. Complex [(eta6-p-cymene) RuCl2(1-kappaP)] (5b) proved to be a particularly attractive catalyst, being both readily available and catalytically active. Substrates with unsubstituted double bonds were cleanly isomerized with this catalyst in 1,2-dichloroethane (0.5 mol-% Ru, 80 C), whereas for those bearing substituents at the double bond (particularly in the position closer to the OH group) lower conversions and selectivities were achieved. A similar trend was noted when pure water was used as the solvent, except that the best results (complete conversion with 2 mol-% Ru) were seen for 1,3-diphenylallyl alcohol, the most hydrophobic substrate.
The reactant in an enzyme-catalyzed reaction is called a substrate. Enzyme inhibitors cause a decrease in the reaction rate of an enzyme-catalyzed reaction.I hope my blog about 37366-09-9 is helpful to your research., SDS of cas: 37366-09-9
Reference£º
Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI