Related Products of 32993-05-8, Chemistry can be defined as the study of matter and the changes it undergoes. You¡¯ll sometimes hear it called the central science because it is the connection between physics and all the other sciences, starting with biology.32993-05-8, Name is Chlorocyclopentadienylbis(triphenylphosphine)ruthenium(II), molecular formula is C41H35ClP2Ru. In a patent, introducing its new discovery.
Polycarbon Ligand Chemistry: Electronic Interactions between a Mononuclear Ruthenium Fragment and a Cobalt-Carbon Cluster Core
The preparation, characterization, and electrochemical response of the complexes Co2(mu-Me3SiC?CC2C?CSiMe 3)(CO)4(dppm) (2) and Co2(mu-Me3SiC2C?CC?CSiMe 3)(CO)4(dppm) (3) are described. Metalation of one of the pendant alkynyl groups in each complex has been achieved, yielding Co2{mu-Me3SiC?CC2C?C[Ru(PPh 3)2Cp]}(CO)4(dppm) (4) and Co2{mu-Me3-SiC2C?CC?C[Ru(PPh 3)2Cp]}(CO)4(dppm) (5). The spectral and electrochemical properties of the heterometallic complexes indicate a significant electronic interaction between the mononuclear fragment and the metallocarbon cluster core. The electronic structure of these compounds has been modeled using DFT, ZINDO, and ELF calculations, and an explanation of the nature of the electronic interaction between the heterometallic fragments is presented.
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Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI