Reference of 301224-40-8. Let¡¯s face it, organic chemistry can seem difficult to learn. Especially from a beginner¡¯s point of view. Like 301224-40-8, Name is (1,3-Dimesitylimidazolidin-2-ylidene)(2-isopropoxybenzylidene)ruthenium(VI) chloride. In a document type is Article, introducing its new discovery.
Synthesis of enantioenriched gamma-quaternary cycloheptenones using a combined allylic alkylation/Stork-Danheiser approach: Preparation of mono-, bi-, and tricyclic systems
A general method for the synthesis of beta-substituted and unsubstituted cycloheptenones bearing enantioenriched all-carbon gamma-quaternary stereocenters is reported. Hydride or organometallic addition to a seven-membered ring vinylogous ester followed by finely tuned quenching parameters achieves elimination to the corresponding cycloheptenone. The resulting enones are elaborated to bi- and tricyclic compounds with potential for the preparation of non-natural analogs and whose structures are embedded in a number of cycloheptanoid natural products.
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Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI