Chemistry is an experimental science, and the best way to enjoy it and learn about it is performing experiments.Introducing a new discovery about 10049-08-8, Name is Ruthenium(III) chloride, Safety of Ruthenium(III) chloride.
The origin of the surprising stabilities of highly charged self-assembled polymetallic complexes in solution
The thermodynamics of electrochemical and complexation reactions involving the heterobimetallic triple-stranded helicates [MA(L5)3]n+ (M = Ru(II), Cr(III) and A = Ca(II), Lu(III)) reveal that solvation processes mask intramolecular intermetallic repulsions in solution, a phenomenon at the origin of the surprising stabilities of highly charged self-assembled polymetallic complexes in solution. A judicious combination of Born-Haber cycles and the Born equation restores the expected electrostatic trend in the gas phase, in which intermetallic interactions can be simply modeled using a standard Coulombic approach. Semiquantitative estimation and prediction of the contribution of the intermetallic repulsion to the total free energy of the formation of discrete polymetallic assemblies in solution become thus accessible. This point is crucial for programming stable metallosupramolecular architectures in solution.
Balanced chemical reaction does not necessarily reveal either the individual elementary reactions by which a reaction occurs or its rate law.Safety of Ruthenium(III) chloride. In my other articles, you can also check out more blogs about 10049-08-8
Reference£º
Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI