In an article, published in an article, once mentioned the application of 15746-57-3, Name is Cis-Dichlorobis(2,2′-bipyridine)ruthenium(II),molecular formula is C20H16Cl2N4Ru, is a conventional compound. this article was the specific content is as follows.category: ruthenium-catalysts
Heteroditopic rhenium(I) and ruthenium(II) bipyridyl calix[4]arene receptors for binding cation-anion ion pairs
New heteroditopic ion pair receptors that contain rhenium(I) and ruthenium(II) bipyridyl amide anion recognition sites covalently linked to a lower rim calix[4]arene tetraester alkali metal cation binding site have been prepared and shown to bind alkali metal (Li+, Na+)-halide (Br-, I-) ion pair species. Proton NMR titration studies reveal the lower rim ester co-bound alkali metal cation significantly enhances the strength of bromide and iodide binding in acetonitrile solutions with the largest positive co-operative binding effect of sixtyfold observed with bromide and the lithium complex of one receptor. Solid/liquid extraction experiments show two of the receptors are capable of solubilising NaCl and NaOAc in dichloromethane solutions. The Royal Society of Chemistry 2001.
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Reference£º
Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI