Children learn through play, and they learn more than adults might expect. Science experiments are a great way to spark their curiosity, get their minds active, and encourage them to do something that doesn¡¯t involve a screen. 10049-08-8, Cl3Ru. A document type is Article, introducing its new discovery., Product Details of 10049-08-8
Complex heterobimetallic salts derived from 1-ethoxycarbonyl-1- cyanoethylene-2,2-dithiolatodioxouranate(VI) ion: Preparation and properties
The reaction of K2[UO2(ecda)2] (generated in situ) with cationic complexes [M(N-N)3]X2 [M = Fe(II), Ru(II), Co(II), Ni(II), Cu(II), Zn(II) or Cd(II); N-N = 2,2′-dipyridyl (dipy), 1,10-phenanthroline (phen) or ethylenediamine (en); ecda2- = 1-ethoxycarbonyl-1-cyanoethylene-2,2- dithiolate; X = Cl-, NO3- or 1/2 SO42-] and n-Pr4NI in 1:1/1:2 molar ratio afforded the complex bimetallic salts [M(N-N)3][UO2(ecda)2] and the complex salt [n-Pr4N]2[UO2(ecda)2], that have been characterized on the basis of elemental analyses, molar conductance and magnetic susceptibility measurements, electrochemical and relevant spectroscopic studies. UV-visible absorption spectra in DMSO support the existence of ion-pair charge transfer (IPCT) absorption band which occurs due to charge transfer interaction between [Fe(phen)3/Ru(dipy)3]2+ and [UO2(ecda)2]2+ion. Temperature dependent (303-373 K) pressed pellet conductivities of the complexes have been studied. All the bimetallic salts of this series comprise discrete tris- chelated octahedral cations [M(N-N)3]2+ and his-chelated dioxouranium(-V1) anion, [UO2(ecda)2]2- with no sign of ligand exchange reaction in solution during the course of their formation.
Interested yet? Keep reading other articles of 10049-08-8!, Product Details of 10049-08-8
Reference£º
Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI