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In an article, published in an article, once mentioned the application of 10049-08-8, Name is Ruthenium(III) chloride,molecular formula is Cl3Ru, is a conventional compound. this article was the specific content is as follows.Recommanded Product: 10049-08-8

Characteristic and electrocatalytic behavior of ruthenium Prussian blue analogue film in strongly acidic media

The remarkable stability of ruthenium Prussian blue analogue (designated as RuOx-PB) in strongly acidic media and for the enzymeless electrocatalytic oxidation of glucose was demonstrated in this study. The RuOx-PB combinative film neither dissolves nor denatures in concentrated acids, such as HClO4, HCl, H2SO4, and HNO3, investigated in this study. The catalytic response was found to directly proportional to [H+]. Such features are unique since neither RuOx- nor PB-based compounds are effective for direct carbohydrate oxidation in acidic media. The RuOx-PB film showed a highly reversible redox peak at ?1.2 V in 5 M HClO4 as a result of the fast proton-coupled electron transfer behavior of high valent ruthenium intermediate, RuVII/VI. The formation of internal multiple-hydrogen bond as well as the generation of the ?RuVII{double bond, long}O species in strongly acidic media were proposed to play a key role in this feature. The RuOx-PB holds high potential for use in catalytic oxidation, corrosion protection, biofuel cell, etc.

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Reference£º
Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI