Reference of 10049-08-8. Let¡¯s face it, organic chemistry can seem difficult to learn. Especially from a beginner¡¯s point of view. Like 10049-08-8, Name is Ruthenium(III) chloride. In a document type is Article, introducing its new discovery.
Efficient synthesis of ruthenium(II) eta5-dienyl compounds starting from Di-mu-chlorodichloro-bis[(1-3eta:6-8eta)-2,7-dimethyloctadienediyl] diruthenium(IV). Versatile precursors for enantioselective hydrogenation catalysts
The dimeric complex di-mu-chlorodichloro-bis[(1-3eta:6-8eta)-2,7-dimethyloctadienediyl] diruthenium(IV) in the presence of base reacts with cyclic and acyclic dienes to the corresponding bis(eta5-dienyl)ruthenium(II) compounds. Crystalline yellow compounds have been isolated ‘in high yields for dienyl = cyclopentadienyl, pentamethylpentadienyl, cycloheptadienyl, indenyl, dimethylpentadienyl, and trimethylpentadienyl.
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Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI