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Reference of 10049-08-8, Catalysts are substances that increase the reaction rate of a chemical reaction without being consumed in the process. 10049-08-8, Name is Ruthenium(III) chloride, molecular formula is Cl3Ru. In a Article£¬once mentioned of 10049-08-8

Kinetics and mechanism of osmium (VIII) and ruthenium (III) catalyzed oxidation of ethanediol and propane 1 : 2 diol with chloramine-T in alkaline and acid media

The kinetics of oxidation of title diols by chloramine-T (CAT) is studied in HCl medium (0.01-0.80 M), catalyzed by Ru(III) chloride at 35 deg C and in NaOH medium (0.001-0.012 M) with OsO4 as catalyst at 50 deg C.Simultaneous catalysis is effected by H+ and Cl- in acid medium in the lower range (0.01-0.15 M), the rate law being -d log /DT = >/<1+k'> which changes to k’1- at medium ranges and becomes independent of at higher acid concentration (>0.4 M).Alkali retards the Os(VIII) catalyzed reaction and the rate law takes the form -d log 1-.Ionic strength and added reaction product, p-toluene-sulphonamide (RNH2) had no significant effect on the reaction rate at lower and high acid concentrations and in alkaline medium, but in the acid range (0.20-0.40 M), increase in ionic stength decreases the rate of oxidation.Decrease in dielectric constant of the reaction medium decreases the rate constant in both media.The reaction was studied at different temperatures and Arrhenius parameters have been evaluated.Suitable mechanisms have been proposed to account for the observed kinetics.

The proportionality constant is the rate constant for the particular unimolecular reaction. the reaction rate is directly proportional to the concentration of the reactant. I hope my blog about 10049-08-8 is helpful to your research., Reference of 10049-08-8

Reference£º
Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI