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Pentakis(methoxycarbonyl)cyclopentadiene Chemistry. Part 7. Preparation and Characterisation of Some Ruthenium Complexes: Crystal and Molecular Structure of eta-Cyclopentadienylruthenium, >
The salt Tl reacts with in acetonitrile to give the complex ; in air the reaction affords >.The crystal structure of the latter has been determined by single-crystal X-ray diffraction methods at 295 K, being refined to a residual of 0.026 for 6 438 ‘observed’ reflections.Crystals are triclinic, space group P1, with a=15.790(5), b=8.968(4), c=7.947(3) Angstroem, alpha=67.52(3), beta=89.52(3), gamma=80.90(3) deg, and Z=2.Both ligands have an eta5 relationship to the ruthenium in what is essentially an eclipsed sandwich compound.For the C5H5 ring, Ru-C is 2.178(2)-2.186(3) Angstroem, while for the C5(CO2Me)5 ligand, Ru-C is 2.157(2)-2.178(2) Angstroem; although these distances are uncorrected for libration, their relativity seems valid.The C5(CO2Me)5 ligand is displaced in reactions with tertiary phosphines in nitrile solvents, and this reaction forms the basis of a process for the oxidation of PPh3 catalysed by the metallocene.The protonation of by HC5(CO2Me)5 is also described.
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Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI