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18-electron ruthenium phosphine sulfonate catalysts for olefin metathesis
The first instances of ruthenium alkylidene complexes based on chelating phosphine sulfonates are presented. Although these complexes are formally 18-electron complexes bearing cis phosphines and cis one-electron donors (sulfonates and chlorides), they are surprisingly active for ring-closing metathesis, cross-metathesis, and ring-opening metathesis polymerization, thus highlighting the unique potential of the sulfonate ligand in the design of a ruthenium metathesis catalyst.
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Reference£º
Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI