Children learn through play, and they learn more than adults might expect. Science experiments are a great way to spark their curiosity, get their minds active, and encourage them to do something that doesn¡¯t involve a screen. 114615-82-6, C12H28NO4Ru. A document type is Article, introducing its new discovery., SDS of cas: 114615-82-6
Reductive alkylation of anhydrides and lactones: Direct access to monosubstituted lactones
Reductive alkylation of anhydrides (1 equiv) with a 2:0.25 mixture of Grignard reagent and Zn(BH4)2 afforded monosubstituted lactones in moderate yields. The same sequence applied to unsubstituted lactones gave monoalkylated diols, which were further selectively oxidised with tetra-n-propylammonium perruthenate (TPAP) into the expected monoalkylated lactones.
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Reference£º
Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI